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Deuterium retention of boron-titanium and reduction of deuterium retention after helium ion irradiations

机译:硼钛的氘保留和氦离子辐照后氘保留的减少

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摘要

Deuterium ion irradiations with an ion with energy of 1.7 keV were conducted for boron-titanium (B-Ti) film prepared by electron beam evaporation and hot pressed titanium-boride, TiB2. The amount of retained deuterium was measured for these materials using a technique of thermal desorption spectroscopy. The amount of deuterium retained in TiB2 was comparable with that in B-Ti. Desorption peaks of deuterium in B-Ti were 470 and 620K, corresponding to a desorption in the low temperature regime observed in boron (B) and a desorption in titanium (Ti), respectively. The desorption peaks in TiB2 were 620K and 750K, which correspond to the desorption in Ti and that in the high temperature regime in B, respectively. The desorption temperature in B-Ti was approximately 100 K lower than that in TiB2. This difference is discussed based upon chemical bindings and crystal structures of B-Ti and TiB2. Irradiation of helium ion with energy of 5 keV was conducted for B-Ti after the deuterium ion irradiation. The amount of retained deuterium decreased and the desorption temperature shifted to the lower temperature regime, as the helium ion fluence increased. The shift to the low temperature regime is due to the enhancement of amorphous structure of B in B-Ti.
机译:对通过电子束蒸发和热压硼化钛TiB2制备的硼钛(B-Ti)膜进行了能量为1.7 keV的氘离子辐照。使用热解吸光谱技术测量了这些材料的氘保留量。 TiB2中保留的氘量与B-Ti相当。 B-Ti中氘的解吸峰分别为470K和620K,分别对应于在硼(B)中观察到的低温状态下的解吸和钛(Ti)中的解吸。 TiB2中的解吸峰分别为620K和750K,分别对应于Ti中的解吸和B中的高温解吸。 B-Ti的解吸温度比TiB2的解吸温度低约100K。基于B-Ti和TiB2的化学键和晶体结构讨论了这种差异。氘离子辐照后,对B-Ti进行5 keV能量的氦离子辐照。随着氦离子通量的增加,氘的保留量减少并且解吸温度转移到较低的温度范围。向低温状态的转变归因于B-Ti中B非晶态结构的增强。

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